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The beauty of the inflationary scenario is that the original state of the universe is relatively immaterial. The exponential expansion so dilutes curvature and particle density that almost any set of initial conditions capable of triggering inflation can lead to a universe that solves the flatness, monopole, and horizon problems. In essence, the universe looks the way that it does because we see only a small part of it. As a bonus, the inflationary hypothesis provides an answer to the question of origin for matter and energy: our universe is composed almost entirely of thermalized vacuum energy left over from the inflationary epoch. These ideas are attractive but the original inflationary universe had a serious problem, as Guth realized in his initial paper. In the original model it was (15.37) in which case the barrier separating the stable and metastable vacuum is comparable with VO.The difficulty with the resulting picture concerns bubbles of true vacuum expanding in the false vacuum. It was shown that two bubbles formed at the same time and separated by a distance greater than 21 would never touch, and the phase transition could not be completed because the exponentially expanding universe would never be covered by bubbles of the new phase. Furthermore, the bubble collisions that did occur would generate a universe that is too inhomogeneous. Thus the original inflationary theory found no graceful exit from the phase transition into a universe that resembles our universe.

Metal-catalyzed oligomerizations are important reactions concerning both their chemistry and practical applications. 12 ,36,37 Since the catalysts [(Ti(IV), Zr(IV), Ni(l), and Ni(lI) complexes] used in coordination polymerization can also be active in oligomerization, catalyst systems and mechanisms will be discussed in more detail in Section 13.2.4. A short discussion of oligomerization with emphasis on the most important processes of practical significance, however, is appropriate here. The first metal-catalyzed ethylene dimerization reaction was accidentally discovered by Ziegler and coworkers while studying ethylene oligomerization to long-chain cx-olefins in the presence of aluminum alkyls 8 They observed that nickel impurities from the reactor caused dimerization instead of oligomerization leading to the formation of I-butene. In fact, the growth reaction (i.e., oligomerization of ethylene) is followed by a displacement reaction by ethylene catalyzed by nickel resulting in the formation of an oligomer and regeneration of the aluminum alkyl. The aluminum-catalyzed chain growth step takes place through insertion into the C-AI bond via a nonsymmetric four-center transition state 9 Nickel,40,41 like almost all metal catalysts (e.g., Ti and Zr) used for alkene dimerization, effects the reaction by a three-step mechanism. 12 Initiation yields an organometallic intermediate via insertion of the alkene into the metal-hydrogen bond followed by propagation via insertion into the metal-carbon bond [Eq. (13.8)]. Intermediate 11 either reacts further by repeated insertion [Eq. (13.9)] or undergoes chain transfer to yield the product and regenerate the metal hydride catalyst through ~-hydrogen transfer [Eq. (13.10)]:

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Required posting of NRC Form 3 Notice to Employees and 10CFR parts 19 and 20 Required instructions to workers concerning risks associated with exposure to radiation Requirement for reporting exposure data to individual workers De nitions of terms for Part 20 Develop radiation protection program to comply with regulations and ALARA

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Allen, E.E., G.W. Tyson, R.J. Whittaker et al. 2007. Genome dynamics in a natural archaeal population. Proc. Natl. Acad. Sci. USA 104:1883 1888. DeLong, E.F., C.M. Preston, T. Mincer et al. 2006. Community genomics among strati ed microbial assemblages in the ocean s interior. Science 311: 496 503. Lo, I., V.J. Denef, N.C. Ver Berkmoes et al. 2007. Strain-resolved community proteomics reveals recombing genomics of acidophilic bacteria. Nature 446:537 541.

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If iMovie starts behaving unstably, you may need to trash your iMovie preferences and repair permissions on your Mac s hard disk. Follow these steps:

1. Select the object to which you want to apply the Feather effect. 2. Choose Effect Stylize Feather to open the Feather dialog box, as shown in Figure 15.16.

Figure 4-7: Clicking the Change Data Source button brings up this dialog box, which enables you to choose a different connection.

With either interaction, you have the same set of actions as you do with other components:

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(continued)

X. Mn-SOD (human) E.C. 1.15.1.1 1n0j (pdb) CO2 800 (pH 7.2) 3.6 10 3 (pH 7.2)

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