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Cyclic amine polymerization, 586 588 Cyclic carbonate polymerization, 585 586 Cyclic ester polymerization, 585 586, 599 600 Cyclic ether polymerization, 548 569 Cyclic sul de polymerization, 588 589 Cyclization: vs crosslinking, 112, 524 526, 545 546 dienes, 524 527 1,3-dienes, 694 696 vs linear step polymerization, 69 74 polymer, 751 752 Cycloaddition polymerization, 183 184 Cycloalkane polymerization, 594 595, 682 683 Cycloalkene polymerization, 589 592, 631 632 Cycloalkyne polymerization, 591 Cyclocopolymerization, 524 527 Cyclodextrin complexes, 299 Cyclopolymerization, 524 527 Cyclosiloxane polymerization, 595 597 Cyclotrimerization, 451 Cyclotriphosphazene, 597 599 Dacron, 94 DADC, see Allyl resin DADM, see Allyl resin DAIP, see Allyl resin DAP, see Allyl resin Darvic, 306 Daughter polymer, 287 Deactivator, 316 Dead-end polymerization, 234 235 Dead polymer, 206 Deashing, 645 Degenerative transfer, 330 de Gennes dense packing, 176 177 Degradative chain transfer, 238, 263 264 Degree of branching, 176, 252 Degree of polymerization. See also Molecular weight Delrin, 448 Dendrimer, 177 180 Dendritic polymer, 174 180 Depolymerization, see Depropagation Depropagation: copolymerization, 515 518 radical polymerization, 279 281 ring-opening polymerization, 562 563 step polymerization, 65 67 Desorption of radicals, 357 360 Diacetylene, 332 Dialkyne, 332 Diethylene glycol bis(allyl carbonate), see Allyl resins

vb.net ocr read text from pdf

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THE UNITED STATES IN THE TWENTIETH CENTURY: 1946 1990

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A plot of the left side of Eq. 3-140b versus time is linear, and the values of z and y can be obtained from the intercept and slope, respectively, if Z 0 and Ri are known. The method

Fig. 3-10 Inhibition of the benzoyl peroxide initiated polymerization of vinyl acetate by duroquinone at 45 C. The three lines are for different concentrations of duroquinone. After Bartlett and Kwart [1950] (by permission of American Chemical Society, Washington, DC).

(continued)

involves dif cult experimentation, since the polymerization rates being measured are quite small, especially if z is large. Figure 3-10 shows Eq. 3-140b plotted for vinyl acetate polymerization inhibited by 2,3,5,6-tetramethylbenzoquinone (duroquinone) [Bartlett and Kwart, 1950]. Table 3-8 shows selected z values for various systems. A careful consideration of Eq. 3-140b shows that for a strong retarder (z ) 1), the polymerization rate will be negligible until the inhibitor concentration is markedly reduced. When the inhibitor concentration becomes suf ciently low, propagation can become competitive with the inhibition reaction. This is more readily seen by considering the equation

d Z z Z d M M 3-141

irst of all, no, you don t need to know anything in this appendix in order to explore circuit-bending Still, you ll be running into schematic diagrams as you move deeper into electronics, and you might even want to chart your own bends using the traditional symbols of the field And these symbols exist for a very good reason Circuitry can get complicated To answer the demands of documenting (and reading) the complex wiring of circuits, the schematic diagram system was developed The goal was to simplify not only component depiction, but wiring depiction as well If the system really works, the drawings in this appendix should aid in your understanding of the most common components appearing on the circuit boards you ll be bending, as well as how they re traditionally depicted within circuitry.

obtained by dividing the rate expression for the disappearance of inhibitor (Eq. 3-134) by that for monomer disappearance (Eq. 3-16). Integration of Eq. 3-141 yields

THE UNITED STATES IN THE TWENTIETH CENTURY: 1946 1990

Z M log z log Z 0 M 0 3-142

where Z 0 and M 0 are initial concentrations. It is apparent from this expression that the inhibitor must be almost completely consumed before the monomer can be polymerized. Equation 3-142 can also be used to determine the inhibition constant from the slope of a plot of log [Z] versus log [M].

(continued)

TABLE 3-8 Inhibitor Constantsa Inhibitor Nitrobenzene Monomerb Methyl acrylate Styrene Vinyl acetate Methyl acrylate Styrene Vinyl acetate Acrylonitrile Methyl methacrylate Styrene Methyl methacrylate (44 C) Styrene Methyl methacrylate (44 C) Acrylonitrile (60 C) Styrene (60 C) Acrylonitrile (60 C) Methyl methacrylate (60 C) Styrene Methyl methacrylate Styrene Methyl methacrylate (44 C) Vinyl acetate (44 C) Methyl acrylate Vinyl acetate Methyl acrylate Vinyl acetate Vinyl acetate Vinyl acetate Vinyl acetate z kz =kp 0.00464 0.326 11.2 0.204 64.2 404 0.91 5.5 (44 C) 518 0.26 2,040 2,000 3.3 536 100 1,027 $11,000 33,000 14,600 0.075 470 0.0001 0.015 0.0002 0.012 0.7 5.0 0.5

vb.net ocr read text from pdf

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vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf

vb.net ocr read text from pdf